sodium phosphate – water technology repo

sodium phosphate – Water Technology Repo

Apr 27, 2015· Two forms of sodium phosphate find application in low and medium pressure boilers; disodium phosphate (NaHPO4 having a 49% P2O5 content) and sodium metaphosphate (NaPO3 having a 69% P2O5 content). Both react under boiler conditions to produce orthophosphate (o-PO4).

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steam generation chemistry: correcting outdated beliefs .

Steam Generation Chemistry: Correcting Outdated Beliefs .

Dec 02, 2015· Thus, congruent phosphate treatment for high-pressure boilers has been discredited, and only tri-sodium phosphate should be utilized. (EPRI and …

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sodium phosphate in treated boiler wat

Sodium Phosphate In Treated Boiler Wat

High-Pressure Steam Cycle and Boiler Water Treatment. 2010-8-3 · ULTRAMARINESM HP BWT Program • Drew Marine pioneered the "modified phosphate-pH treatment" – Utilizes disodium orthophosphate and caustic so that no "free caustic" is generated in the boiler water – Sodium to phosphate ratio is approximately 2.75:1 and provides margin of safety for good control of the …

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water handbook - preboiler & industrial boiler corrosion .

Water Handbook - Preboiler & Industrial Boiler Corrosion .

Phosphate buffers the boiler water, reducing the chance of large pH changes due to the development of high caustic concentrations. Excess caustic combines with disodium phosphate and forms trisodium phosphate. Sufficient disodium phosphate must be available to combine with all of the free caustic in order to form trisodium phosphate.

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modelling of phosphate hideout in utility boilers .

Modelling of phosphate hideout in utility boilers .

Phosphate based boiler water treatment programs continue to be widely utilized in utility power cycles. While this treatment scheme has a number of beneficial aspects, phosphate hide-out can be troublesome in some boilers. EPRI-sponsored laboratory testing of sodium phosphate boiler water treatment provided data on phosphate hide-out.

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boiler water - wikiped

Boiler water - Wikiped

Boiler sludge concentrations created by coagulation treatment may be avoided by sodium phosphate treatment when water hardness is less than 60 mg/L. With adequate alkalinity, addition of sodium phosphate produces an insoluble precipitate of hydroxyapatite with magnesium hydroxide and magnesium and calcium silicates.

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co-ordinated and congruent phosphate treatment of boiler ?

Co-ordinated And Congruent Phosphate Treatment Of Boiler ?

However, a small proportion of the NaOH always remains. Congruent treatment tries to avoid this by making a mix so that the Na+ to PO-34 ion ratio never exceeds 2.6 : 1 ( Na3PO4 has a sodium to phosphate ratio of 3 : 1 ) Co-ordinated phosphate treatment •

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5-2 recovery boiler water treatme

5-2 Recovery Boiler Water Treatme

Recovery Boiler Water Treatment January 2008 Presented By Sheppard T. Powell Associates, LLC Baltimore Maryland www.stpa.com Presentation Format ... Phosphate Effect on Boiler Water pH Sodium-To-Phosphate Molar Ratio Blowdown Phosphate, mg/L p H NaOH TSP DSP (MSP) 3 . 0 2 . 6 2 . 4 2. 2 . 1 2 . 0

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big picture of water treatment chemica

Big Picture of Water Treatment Chemica

Alkalinity Control: maintaining proper boiler alkalinity or pH protects the boiler from corrosion and facilitates certain types of chemical treatment programs (e.g., phosphate precipitation programs). Caustic (sodium hydroxide) Mono -, di , and trisodium phosphate (coordinated phosphate control) Polymers: disperse solids and inhibit scale.

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boiler feedwater treatment (part i): why water treatment .

Boiler Feedwater Treatment (Part I): Why Water Treatment .

The feedwater (make-up water) from outside needs to be treated for the reduction or removal of impurities by first filtration, and then followed by softening, evaporation, deariation, ion exchange etc. Internal treatment is also required for the conditioning of impurities within the boiler system, to control corrosion, as reactions occur in the ...

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boiler water treatment - lennte

Boiler water treatment - Lennte

When the amount of sludge is not high (low feed water hardness) it is preferable to use a higher percentage of phosphates in the treatment. Phosphates form separated sludge particles. A higher percentage of organic sludge dispersants is used in the treatment to keep the sludge particles dispersed throughout the boiler water.

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boiler water treatment - hartford steam boiler inspection .

Boiler Water Treatment - Hartford Steam Boiler Inspection .

Hartford Steam Boiler Boiler Water Treatment Phosphate compounds are common additives for boiler water treatment. Phosphate compounds react with any remaining hard water compounds to create a soft sludge that is eliminated through blowdown. Trisodium phosphate is the most common compound for lower pressure boilers. Phosphates also

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using of congruent phosphate as equilibrium phosphate .

Using of congruent phosphate as equilibrium phosphate .

The most popular treatment for low pressure boilers (< 600 psi) is dosing of tri-sodium phosphate (TSP), it reacts with water at high temperature and gives sodium hydroxide to increase boilers water pH as shown in equation (1). 3 4 2+ →2 4+Na PO H O Na HPO NaOH(1) To prevent formation of free sodium hydroxide the pH and phosphate concentration have to be kept below the line corresponds …

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sodium phosphate in treated boiler wat

sodium phosphate in treated boiler wat

2017-10-10 · nation in caustic-treated boiler water. The cation column converts sodium hydroxide to water and removes the background conductivity. Cation conductivity cannot be used to measure contamination in phosphate-treated boiler water because the phosphate salts are converted to phosphoric acid, which has high conductivity. Get A Quote

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phosphate hideo

Phosphate Hideo

When the concentration of phosphate in the boiler water is too high, phosphate will react with boiler scale forming iron and iron sodium phosphates or precipitate to form a solid phase on the hot boiler tube surfaces and elsewhere.

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(pdf) using of congruent phosphate as equilibrium .

(PDF) Using of congruent phosphate as equilibrium .

Oct 02, 2020· Equilibrium phosphate control is based on boilers water treatment by tri-sodium phosphate for low pressure boilers and tri-sodium phosphate added low concentration of sodium …

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inferred ph in steam plant water chemistry monitori

Inferred pH in Steam Plant Water Chemistry Monitori

Common boiler water treatment chemicals are sodium hydroxide and sodium phosphate salts. They are used to adjust boiler water pH to reduce corrosion and buffer the water against acid-forming contaminants. Boiler water chemicals by and large remain in the boiler. However, vaporous and mechanical carryover do introduce trace amounts into the steam.

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trisodium phosphate - an overview | sciencedirect topi

Trisodium Phosphate - an overview | ScienceDirect Topi

Caustic cracking of boilers had been mitigated by employing welding (instead of riveting) and/or by adding inhibitors (such as sodium sulphate, trisodium phosphate, sodium nitrate, tannin, lignosulphates, etc.) into the boiler water [9]. However, caustic cracking continues to be a problem wherever stressed steel comes in contact with hot alkaline solutions.

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ep0640747a1 - boiler system ph/phosphate program control .

EP0640747A1 - Boiler system pH/phosphate program control .

A pH/phosphate program in a boiler water system is controlled by: (1) determining the feed rate of the phosphate to the boiler by adding to a phosphate-feed stream containing the phosphate feeding to the boiler a phosphate-feed tracer in known proportion to the phosphate, determining the concentration of the phosphate-feed tracer in the phosphate-feed stream and correlating the phosphate-feed ...

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disadvantages of trisodium phosphate dosing ... - cfbc boil

disadvantages of trisodium phosphate dosing ... - CFBC Boil

The water used in high pressure steam plants is Inferred pH in Steam Plant Water Chemistry Monitoring conductivity in phosphate treated boilers. one mole of trisodium phosphate will increase boiler water pH Correcting the dosage of phosphate if the Although high pressure boilers and the

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water treatment - phosphate specialty : phosphate special

Water Treatment - Phosphate Specialty : Phosphate Special

Boiler feedwater can be protected from corrosive conditions through coordinated phosphate/pH control treatment. Phosphate buffers the boiler water, reducing the chance of large pH swings due to the development of caustic concentrations. In phosphate treatment, excess caustic combines with disodium phosphate to form trisodium phosphate.

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